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Q.

The osmotic pressure of a phenol solution in an organic solvent is deternined to be 20% less than expected, it is due to

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a

Phenol is 20% ionised

b

Phenol is 20% dimerised

c

Phenol is 40% dimerised

d

Phenol is 80% dimerised

answer is C.

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Detailed Solution

Phenol in an organic solvent 2A    A2 dimenstion π=iCRT if 20% reduced, left 80%. for 40% dimension α = i -1 12-1 = 0.4=i-112-1 -0.2 = i-1 i = 0.8 So, now π=0.8CRT 

Hence, the correct option is: (C) phenol is 40% dimerised

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