The osmotic pressure of an ionic substance XY is in water is four times that of 0.01M BaCl2 at same temperature. Concentration of XY (in mole lit-1) is (assume 100% ionisation in XY and BaCl2)

πxy=4×πBaCl2i×CRT=4×i×CRT2×[xy]=4×3×0.01[xy]=12×0.012=6×10−2

The osmotic pressure of an ionic substance XY is in water is four times that of 0.01M BaCl2 at same temperature. Concentration of XY (in mole lit-1) is (assume 100% ionisation in XY and BaCl2)

πxy=4×πBaCl2i×CRT=4×i×CRT2×[xy]=4×3×0.01[xy]=12×0.012=6×10−2

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The osmotic pressure of an ionic substance XY is in water is four times that of 0.01M BaCl₂ at same temperature. Concentration of XY (in mole lit^-1) is (assume 100% ionisation in XY and BaCl₂)

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4×10^-2

16×10^-4

4×10^-4

6×10^-2

answer is D.

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Detailed Solution

$\begin{array}{l} π_{xy} = 4 \times π_{{BaCl}_{2}} \\ i \times CRT = 4 \times i \times CRT \\ 2 \times [xy] = 4 \times 3 \times 0.01 \\ [xy] = \frac{12 \times 0.01}{2} = 6 \times 10^{- 2} \end{array}$

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The osmotic pressure of an ionic substance XY is in water is four times that of 0.01M BaCl2 at same temperature. Concentration of XY (in mole lit-1) is (assume 100% ionisation in XY and BaCl2)

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The osmotic pressure of an ionic substance XY is in water is four times that of 0.01M BaCl₂ at same temperature. Concentration of XY (in mole lit^-1) is (assume 100% ionisation in XY and BaCl₂)