Q.

The oxidation number of ‘Mn’ in KMnO4 is

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a

+7

b

+3

c

0

d

+4

answer is D.

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Detailed Solution

The compound KMnO₄ (Potassium Permanganate) contains:

  • 1 Potassium atom (K)
  • 1 Manganese atom (Mn)
  • 4 Oxygen atoms (O)

To determine the oxidation number of Mn in KMnO₄, we use the following steps:

Step-by-Step Calculation:

  1. Oxidation Numbers of Known Elements:
    • Potassium (K) is in Group 1, so its oxidation number is +1.
    • Oxygen (O) generally has an oxidation number of -2 (except in peroxides or superoxides).
  2. Total Charge of KMnO₄: KMnO₄ is a neutral compound, so the sum of oxidation numbers of all its atoms is 0.
  3. Let the Oxidation Number of Mn be x: The total oxidation number equation is:

    (Oxidation number of K) + (Oxidation number of Mn) + (Oxidation number of O × Number of O atoms) = 0

    Substituting the values:

    (+1) + x + (-2 × 4) = 0
  4. Simplify the Equation:

    1 + x - 8 = 0
    x = 8 - 1
    x = +7

Final Answer:

The oxidation number of Mn in KMnO₄ is +7.

Explanation with Keyword Usage:

In KMnO₄, the kmno4 oxidation number of manganese (Mn) is calculated using the rules of oxidation numbers and the neutrality of the compound. Potassium contributes +1, and each oxygen contributes -2. Solving for manganese gives an oxidation number of +7, which indicates that Mn in KMnO₄ is in a highly oxidized state.

The kmno4 oxidation number concept is essential for understanding redox reactions, where KMnO₄ often acts as a strong oxidizing agent due to Mn's high oxidation state of +7. Thus, identifying the kmno4 oxidation number helps in predicting its chemical behavior in reactions.

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The oxidation number of ‘Mn’ in KMnO4 is