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Q.

The oxidation of phenol with chromic acid gives.

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a

an aldehyde

b

a conjugated diketone

c

a simple diketone

d

ortho benzoquinone

answer is B.

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Detailed Solution

Oxidation of Phenol with Chromic Acid

When phenol is oxidized by chromic acid, it undergoes transformation to form benzoquinone.

Phenol (C6H5OH) is converted into benzoquinone (C6H4O2) which contains two conjugated carbonyl groups.

Reaction:

Phenol → Benzoquinone

This product is also called p-benzoquinone or 1,4-benzoquinone due to the para positioning of ketone groups on the aromatic ring.

The oxidation involves conversion of hydroxyl groups to carbonyls, resulting in a conjugated diketone.

 

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The oxidation of phenol with chromic acid gives.