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Q.

The oxide that does not act as an insulator even by a change in temperature

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a

VO2

b

TiO

c

VO

d

TiO2

answer is B.

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Detailed Solution

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  • Due to the lower nuclear charge of Ti its 3d orbitals are less contracted than that of Fe, Co, and Ni, which allows for overlapping of the 3d orbitals and the formation of a metal d band in TiO. 
  • The d electrons of Ti2+ partially fill this band and lead to electrical conductivity.
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The oxide that does not act as an insulator even by a change in temperature