Q.

The oxoanion which contains all equivalent M-O bond is :
(I) CrO42- (II) MnO4- (III) Cr2O72-

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a

III only

b

I, II, III

c

I only

d

I, II

answer is C.

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Detailed Solution

In CrO42-, all Cr-O bonds are equal and has the same bond energy. Similarly, bond strength of all Mn-O bonds in MnO4-.is same because all Mn-O bonds are equal. But in Cr2O72-, there are two Cr-O bonds of different bond strength because the bond length of one Cr-O is 179 pm and other is 163 pm.

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