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The pair having similar geometry is

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BF₃, NH₃

H₂O, C₂H₂

CO₂, SO₂

NH₃, PH₃

answer is D.

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Detailed Solution

(A) BF₃ is sp²hybridised(trigonal planar) and NH₃ is sp³ hybridized(pyramidal due to one lone pair)

(B) H₂O is sp³ hybridized(angular due to two lone pairs) , C₂H₂ is sp hybridized(linear).

(D) Both NH₃ and PH₃ are sp³ hybridised and exhibit tetrahedral geometry.

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