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Q.

The pair having similar geometry is  
(a) PCl3,NH3  (b) BeCl2,SnCl2        
(c)  SiCl4,CCl4 (d)  XeF4,SF4

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a

a and c 

b

 a,b and c

c

b and d        

d

a and d

answer is A.

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Detailed Solution

(a) PCl3,NH3  - both are pyramidal 
(b)  BeCl2is linear while  SnCl2is angular
(c) SiCl4,CCl4 - both are tetrahedral 
d) XeF4 is square planar while SF4 has See saw geometry.
 

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