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Q.

The pair in which both the species have same magnetic moment (spin only) is.

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a

[CoCl4]2,  [Fe(H2O)6]2

b

[Mn(H2O)6]2+,[Cr(H2O)6]2+

c

[Cr(H2O)6]2+,[Fe(H2O)6]2+

d

[Cr(H2O)6]2+,[CoCl4]2

answer is C.

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Detailed Solution

In [Cr(H2O)6]2+and[Fe(H2O)6]2+H2O is a weak field ligand. Hence ,it will not pair up the electrons in metals orbital.
Cr2+=[3d44s0]            
 Question Image
Fe2+=[3d64s0]
Question Image          
Both have 4 unpaired electrons in d- orbital.
μ=n(n+2)   BM μ=24BM.

Therefore, both have same magnetic moment (BM).
 

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