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Q.

The pair of ions which do not have diamagne-tic nature

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a

Cu1+ and Zn2+

b

Ca2+ and Zn2+

c

Sc3+ and Ti4+

d

V2+ and Fe2+

answer is D.

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Detailed Solution

(A) Cu1+ (4s03d10) and Zn2+([Ar]4s03d10) --- both are diamagnetic(due to    completely filled configuration)

(B) Sc3+ ([Ar]4s03d0) and Ti4+ ([Ar]4s03d0) --- both are diamagnetic

(C) Ca2+([Ar]4s0) and Zn2+([Ar]4s03d10) --- both are diamagnetic

(D) V2+([Ar]4s03d3)and Fe2+([Ar]4s03d6) --- both are paramagnetic(due to the presence of unpaired electrons)

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