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Q.

The pale colour of [Mn(H2O)6]2+ is due to

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a

intra ligand excitation

b

metal to ligand charge transfer

c

spin forbidden d-d transition

d

ligand to metal charge transfer

answer is A.

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Detailed Solution

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In [Mn(H2O)6]2+,Mn is in +2 oxidation state with d5 configuration and  t2g3 and eg2 electron distribution. Since all the d orbitals are filled with one electron each the d-d electron transition is spin forbidden.

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The pale colour of [Mn(H2O)6]2+ is due to