Q.

The percentage of hydrolysis of 0.003 M aqueous solution of NaOCN  (Ka  for  HOCN  is  3.33×10-4M) is :

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a

0.01     

b

0.1

c

0.001

d

1          

answer is C.

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Detailed Solution

NaOCN is a salt of weak acid and strong base 

Kh=KwKa=1×10-143.33×10-4=0.300×10-10=3.0×10-11

Degree of hydrolysis

h=KhC

=3.0×10-110.003=3.0×10-113.0×10-3=10-8=1×10-4

Percentage of hydrolysis = degree of hydrolysis  x 100

=1×10-4×102=10-2=0.01%

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