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Q.

The plot of osmotic pressure (π) vs concentration (mol L–1) for a solution gives a straight line with slope 25.73 L bar mol–1. The temperature at which the osmotic pressure measurement is done is:  (Use R=0.083Lbarmol1K1 ) 

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a

37C

b

12.05C

c

310C

d

25.73C

answer is C.

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Detailed Solution

π=CRT+0y=mx+C
 Slope (m)=RT=25.73Lbarmol1
T=25.73Lbarmole1RT=25.73Lbarmole10.083Lbarmole1K1T=37C

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