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Q.

The polarimeter readings in an experiment to measure the inversion of cane sugar were as follows
 

Time (minutes)030
Rotation due to solution (degree)3020-15

Given 
[log2=0.3,log3=0.48log7=0.84, ]
Identify the correct statement. 

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a

The solution is optically inactive at 90 minutes

b

The half life of the reaction is 60 minutes

c

The solution is optically inactive at 120 minutes

d

The half life of the reaction is 90 minutes

answer is C.

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Detailed Solution

k=2.303tlog[rr0rrt]  k=2.30330log[15301520]   k=2.30330log[97] =9.21×103  t1/2=0.693k  t1/275mint. Let solution becomes optically inactive after a time (t). So [rt=0] k=2.303tlog[1530150]   k=2.303tlog3   k=2.3039.21×103×0.48 t120mint

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