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Q.

The potential of the Daniell cell, 

Zn|ZnSO4(1M)||CuSO4(1M)|Cu  was reported by Buckbee, Surdzial, and Metz as 

Eo=1.10280.641×103T+0.72×105T2, where T is the Celsius temperature. Calculate ΔSo for the cell reaction at 25oC

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a

-25.43

b

-55.39

c

-45.32

d

-34.52

answer is D.

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Detailed Solution

dEodT=0.641×103+2×0.72×105TΔS=2×96500×[0.647×103+2×0.72×105×25]=55.39

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