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Q.

The product (C) in the below mentioned reaction is :
 CH3CH2CH2BrΔKOH(alc)AHBrBKOH(aq)ΔC

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a

Propyne 

b

Propene

c

Propan-2-ol 

d

Propan-1-ol 

answer is D.

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Detailed Solution

Reaction Product Sequence: Propan-2-ol

Product (C) in the Reaction Sequence

CH3–CH2–CH2–Br

alc. KOH, Δ → A

HBr → B

aq. KOH → C

Product C is propan-2-ol (CH3–CH(OH)–CH3)

Stepwise mechanism:

1. Alcoholic KOH eliminates HBr to yield propene (CH3–CH=CH2).

2. HBr adds to propene (Markovnikov rule) to give 2-bromopropane (CH3–CHBr–CH3).

3. Aqueous KOH replaces Br with OH to yield propan-2-ol (CH3–CH(OH)–CH3).

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