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Q.

The product of the following  reaction is:

Na2S+Na2Fe(CN)5NO

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a

A purple coloured complex with +2 oxidation state of Fe.

b

A brown coloured complex with +3 oxidation state of Fe.

c

A brown coloured complex with +1 oxidation state of Fe.

d

A yellow coloured complex with +2 oxidation state of Fe.

answer is A.

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Detailed Solution

The product obtained after the reaction is Na4Fe(CN)5NOS(purple colored).

With sodium nitroprusside solution, ionic sulfide gives a purple color in an alkaline medium.

Na2S+Na2Fe(CN)5NONa4Fe(CN)5NOS

Here X is Na4Fe(CN)5(NOS)

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