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Q.

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The products AB and B are

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a

CH3-CH2-CH2-CH2-COONa, CHCl3

b

CH3-CH-CH-CH3 ; CHCl3 + CO2

c

CH3-CH2-CH2-CH3 ; CHCl3 + CO2

d

CH3-CH=CH-CH2-COONa, CHCl3

answer is B.

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Detailed Solution

It is haloform test

-CH3 group of -CO-CH3 gets halogenated first to form -CO-CX3.

-CO-CX3 undergoes alkaline hydrolysis to give haloform and a carboxylic acid with one carbon lesser than the parent is formed during which C = C is not oxidized.

CH3-CH=CH-CH2-CO-CH3 NaOCl CH3-CH=CH-CH2-COONa + CHCl3

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