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Q.

The product(s) obtained via oxymercuration  HgSO4+H2SO4 of 1-butyne would be

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a

CH3CH2COCH3

b

CH3CH2CH2CHO

c

CH3CH2CHO+HCHO

d

CH3CH2COOH+HCOOH

answer is A.

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Detailed Solution

CH3CH2CCHHgSO4H2SO42HOCH3CH2C(OH)2CH3H2OCH3CH2CCH3

1-butyne reacts with mercurous sulphide and sulfuric acid to produce isobutyl alcohol, which then passes through tautomerism to produce ethyl methyl ketone.

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