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Q.

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aquecous solutions KCl,CH3OH and CH3CH211OSO3Na+ at room temperature. The correct assigment of the sketches
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a

I:KCl    II:CH3OH    III:CH3CH211OSO3Na+

b

 I : CH3CH211OSO3Na+    II : CH3OH     III : KCl

c

I) KCl II) CH3CH211OSO3Na+  III : CH3OH

d

 D) I : CH3OH  II : KCl  III: CH3CH211OSO3Na+

answer is D.

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Detailed Solution

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For KCl curve – Increase of surface tension for inorganic salts.For CH3OH curve – Decrease of surface tension progressively for alcohols For CH3CH211OSO3Na+ curve – Decrease of surface tension before CMC (Critical Micelle Concentration) and then almost unchanged

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