Q.

The question has two statements. Statement I and statement II.

Statement I: The metal-carbon bond in metal carbonyls possess σ character only.
Statement II: In metal carbonyls, the M – C σ bond is formed by the donation of a pair of electrons from a filled d orbital of metal into the vacant antibonding  π* orbital of carbon monoxide.

 In light of the given statements, choose the most appropriate answer from the options given below.

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a

 Both statement I and statement II are correct.

b

Statement I is incorrect but statement II is correct.

c

Statement I is correct but statement II is incorrect.

d

Both statement I and statement II are incorrect.

answer is B.

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Detailed Solution

In metal carbonyls, the metal-carbon bond possess both σ - π character. The M - C σ bond is formed by the donation of lone pair of electrons on the carbonyl carbon into a vacant orbital of the metal. The M-C π bond is formed by the donation of a pair of electrons from a filled d orbital of metal into the vacant antibonding π* orbital of carbon monoxide.

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