Q.

The radial probability distribution curve obtained for an orbital wave function has 3 peaks and 2 radial nodes. The valence electron of which one of the following metals does this wave function correspond to ?

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a

Na

b

Li

c

K

d

Cu

answer is D.

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Detailed Solution

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  • Since the radial probability distribution curve has 3 peaks, it means that for it n=3 and l=0.
  •  Moreover, it has two radial nodes ie, n−l−1=2, which also satisfied the previous condition, ie, 3−0−1=2
  • Hence, the valence electron of the metal must present in 3s−orbital

Element                   Configuration             

            

Cu29                            1s22s22p63s23p63d104s1

Li3                                1s22s1

K19​                              1s22s22p63s23p6

Na11​                            1s22s22p63s1

Only the valence electron of Na11​ is in 3s orbital
 

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