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Q.

The radial probability distribution curve obtained for an orbital wave function (ψ) has 3 peaks and 2 radial nodes. The valence electron of which one of the following metals does this wave function (ψ) correspond to ?

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a

Na

b

Co

c

Li

d

K

answer is D.

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Detailed Solution

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Since the radial probability distribution curve has 3 peaks, it means that for it n=3 and l=0. Moreover, it has two radial nodes ie, n−l−1=2, which also satisfied the previous condition, ie, 3−0−1=2. Hence, the valence electron of the metal must present in 3s−orbital

Valence shell electronic configurations of given options are,

Cu - [Ar]3d104s1

Li - [He]2s1

K - [Ne]4s1

Na - [He]3s1

Hence 'Na' is the suitable answer.

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