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Q.

The radius of the first permitted Bohr orbit for the electron, in a hydrogen atom equals 0.51 A0 and its ground state energy equals - 13.6 e V. If the electron in the hydrogen atom is replaced by muon (μ-1)) [Charge same as electron and mass 207 me], the first Bohr radius and ground state energy will be [NEET (Odisha) 2019]

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a

0.53 X 10-13 m, -3.6 eV

b

2.56 x 10-13 m, -13.6 eV

c

2.56 X 10-13 m, - 2.8 keV

d

25.6 X 10-13 m, - 2.8 eV

answer is C.

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Detailed Solution

Given, radius of first orbit for electron r1 = 0.51A0

Ground state energy of electron, E1- 13.6 e V
Mass of electron = me
Mass of muon, mμ = 207m.
Mass of nucleus, M = 1836me
When electron in hydrogen atom is replaced by muon, the reduced mass of muon is

mμ'=mμMmμ+M           …(i)

Substituting the given values in Eq. (il, we get

mμ'=207me×1836me207me+18β6me186me          …(ii)

The radius of first orbit in hydrogen atom for electron is given by

r1=h2ε0πmee2                      …(iii)

The radius of first orbit for muon is given by

r1'=h2ε0πmμ'e2   charge of μ= charge of e-

=h2ε0π×186mee2     [from Eq. (ii)]

=h2ε0πmee21186=r1186  [from Eq. (iii)]

=0.51186 A0                    r1=0.51 A0

=2.74×10-13 m   1 A0=10-10 m

The total energy of electron is given by

En=-mZ2e48ε02h21n2

  Enm

For electron in first orbit of hydrogen atom,

E1=kme                       …(iv)

 where, k=e48ε02h2= constant. 

For muon in first orbit,

E1'=kmμ' 

=k×186me       [from Eq. (ii)]

=186 kme

=186E1             [from Eq. (iv)]

=186(-13.6)eV   (given, E1-13.6 eV)

- 2529.6 eV = - 2.5 keV

These values are closest to that of option (c).

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