Q.

The rate constant for a reaction at 400K and 500K are 2.60×105s1 and 2.60×103s1 respectively.The activation  energy of the reaction in  Kjmol1 is

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a

76.6

b

38.3

c

57.4

d

114.9

answer is D.

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Detailed Solution

Given k1=2.60×105s1,k2=2.60×101s1

T1=400K,T2=500K

According to Arrhenius equation

logk2k1=Ea2.303RT2T1T1T2

log2.60×1032.60×105=Ed2.303×8.314
Ea=2×2.303×8.3100

Ea=76.6×103J/mol

Ea=76.6Kj/mol

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The rate constant for a reaction at 400K and 500K are 2.60×10−5s−1 and 2.60×10−3s−1 respectively.The activation  energy of the reaction in  Kj mol−1 is