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Q.

The rate constant for two parallel reactions were found to be    1.0 × 10-2dm3 mol-1s-1 and 3.0 × 10-2 dm3mol-1s-1. If the corresponding energies of activation of  the parallel reactions are 60. 0 kJ mol-1 and 70.0kJ mol-1respectively what is the apparent  overall energy of activation.  

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a

130.0 kJ mol-1

b

65.0 kJ mol-1

c

67.5 kJ mol-1

d

100 kJ mol-1

answer is C.

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Detailed Solution

Ea = k2E2 + k1E1k2 + k1

= 1.0 × 10-2 × 60 + 3.0 × 10-2 × 701.0 × 10-2 + 3.0 × 10-2

Ea = 67.5 kJ mol-1

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The rate constant for two parallel reactions were found to be    1.0 × 10-2dm3 mol-1s-1 and 3.0 × 10-2 dm3mol-1s-1. If the corresponding energies of activation of  the parallel reactions are 60. 0 kJ mol-1 and 70.0kJ mol-1respectively what is the apparent  overall energy of activation.