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Q.

The rate constant is doubled when temperature increases from 270C to 370C. Activation energy in kJ is

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a

100

b

54

c

34

d

50

answer is B.

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Detailed Solution

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We are given that:

When T1​=27+273=300K

Let k1​=k

When T2​=37+273=310K

k2​=2k

Substituting these values the equation:

log K2K1=2.303 Ea(T2-T1T1T2)

We will get:

log2KK(Ea2.303×8.314)×310-300310×300

log 2(Ea2.303×8.314)×10300×310

Ea​=53598.6 Jmol−1

Ea​=53.6 kJmol−1

Hence, the energy of activation of the reaction is 53.6 kJmol−1

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