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Q.

The rate constant is doubled when temperature increases from 27°C to 37°C. Activation energy in kJ is

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a

100

b

54

c

34

d

50

answer is B.

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Detailed Solution

We are given that:

 When T1=27+273=300K  Let k1=k  When T2=37+273=310K k2=2k  Substituting these values the equation:  logk2k1=Ea2.303×T2T1T1T2  We will get:  log2kk=Ea2.303×8.314310300300×310 log(2)=Ea2.303×8.31410300×310 Ea=53598.6Jmol1 Ea=53.6kJmol1

Hence, the activation energy of the reaction is 53.6 KJ which is equal to 54 KJ.

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