Q.

The rate constant, the activation energy and Arrhenius parameter of a chemical reaction at 25°C are 3.0×104s1,1044 kJ mol1 and 6.0×1014s1 respectively. The value of the rate constant as T is

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a

2.0×1018s1

b

6.0×1014s1

c

3.6×1030s1

d

Infinity

answer is B.

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Detailed Solution

The Arrhenius equation is 

K=AeEa/RT

As T the value EaRT0

& eEa/RTe01

Hence kA

Hence k=6.0×1014s1

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