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Q.

The rate equation for the reaction  2A+BC is found to be : rate  =k[A][B]. The correct statement in relation to this reaction is :

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a

unit of k must be sec-1

b

t1/2 is a constant

c

rate of formation of C is twice the rate of disappearance of A

d

value of k is independent of initial concentrations of A and B

answer is D.

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Detailed Solution

The reaction is first order in A and first order in B, according to the rate equation rate = k[A][B]. In light of this, the reaction's overall order is 2.
(A) The concentration of A and B at the start has no effect on the value of k. Consequently, assertion B is true.
(B) The half-life time is variable. It varies inversely with the concentration of the reactants. Therefore, statement B is untrue.
(C) The rate of production of C is half that of A's rate of extinction.

d[C]dt=d[A]2dt

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