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Q.

The rate expression for the reaction A(g)+B(g) C(g)is rate =kCA2CB1/2. What changes in the initial concentrations of A and B will cause the rate of reaction to increase by a factor of eight?

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a

CA×2;CB×2

b

CA×2;CB×4

c

CA×1;CB×4

answer is B.

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Detailed Solution

A(g)+B(g)C(g)

 rate           =KCA2CB1/2 Increase   =8  In the case of CA × 2 and  CB × 2, we can say that k=(2CA)2×(4CB)1/2 =[22CA2]×[41/2CB1/2]k=4×2×CA2CB1/2 =8CA2CB1/2 B:CA×2;CB×4

 

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