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Q.

The rate law for the reaction RCl+NaOH(aq)ROH+NaCl

rate =KRCl The rate of reaction will be

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a

unaffected by increasing temperature of the reaction

b

doubled on doubling the concentration of NaOH

c

halved on reducing the concentration of NaOH to half

d

halved on reducing the concentration of RCl to half

answer is D.

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Detailed Solution

 

For the reaction RCl+NaOH(aq)ROH+NaCl

rate =KRCl

Here, the rate of reaction depends on concentration of RCl only but not on NaOH solution. The rate of reaction depends on temperature. If we increase temperature then rate of reaction is increased. 1 Initial rate r1=Kxeqn(1)  If reducing the concentration of RCl to half, then the rate will Become 

Final rate r2=Kx/2eqn(2)

From equations 1 and 2,

r1r2=K[x]K[x/2]

r1r2=2

r2=r12

Therefore, on reducing the concentration of RCl to half the rate of reaction would become halved.

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