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Q.

The rate of a reaction doubles, when its temperature changes from 300 K to 310 K. Activation energy of such a reaction will be R=8.314JK1mol1and log 2=0.301)

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a

53.6 kJ mol1

b

58.5 kJ mol1

c

48.6 kJ mol1

d

60.5 kJ mol1

answer is A.

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Detailed Solution

From Arrhenius equation, log k2k1=Ea2.303R1T21T1
Given, k2k1=2,T2=310 K and T1=300 K
On putting values,
            log 2=Ea2.303×8.31413101300
           Ea=53598.6J/mol53.6kJ/mol

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The rate of a reaction doubles, when its temperature changes from 300 K to 310 K. Activation energy of such a reaction will be R=8.314JK−1mol−1and log 2=0.301)