The rate of chemisorption :

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is independent of temperature

decreases with increase of pressure

increases with increase of pressure

is independent of pressure

answer is B.

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Detailed Solution

The flow of chemical species that are incident on the substrate surface affects the rate of chemisorption. High chemisorption rate is caused by high incident flux. Because species with short diffusion paths have lower incident fluxes, the rate of chemisorption decreases as pressure is raised.

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