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Q.

The rate of the reaction 2NO+O22NO2 at 25°C is 0.028 mol L-1S-1.The experimental rate is given by r=KNO2O2. If the initial concentrations of the reactants are O2=0.040 mol L-1 and NO=0.01 mol.L-1,the rate constant of the reaction is

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a

7.0'10-4L2mol-2S-1

b

7.0' 103L2mol-2S-1

c

7.0' 102L2mol-2S-1

d

7.0' 10-2L mol-1S-1

answer is D.

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Detailed Solution

From rate law expression, Rate,r=KNO2O2eqn(1) 

As per given information,

O2=0.04mol.L-1 and NO=0.01 mol.L-1

And rate of reaction , r=0.028 mol.L-1.S-1

And then

0.028=k0.0120.040

K=0.0280.0120.04=7.0×103L2.mol-2.S-1

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