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Q.

The rate of the reaction ${CCl}_{3} CHO + NO \to {CHCl}_{3} + NO + CO$ is given by Rate $= K [{CCl}_{3} CHO] [NO]$ . If concentration is expressed in moles/litre, the units of K are

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a

${sec}^{- 1}$

b

${litre mole}^{- 1} {sec}^{- 1}$

c

${litre}^{2} {mole}^{- 2} {sec}^{- 1}$

d

${mole litre}^{- 1} {sec}^{- 1}$

answer is C.

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Detailed Solution

It is a second-order reaction and the unit of k for second order reaction is litre ${mol}^{- 1} {sec}^{- 1} .$

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The rate of the reaction CCl3CHO+NO→CHCl3+NO+CO is given by Rate =K[CCl3CHO][NO]. If concentration is expressed in moles/litre, the units of K are