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Q.

The ratio of Pi bonds to sigma bonds in benzene is

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a

1:4

b

1:3

c

1:2

d

1:1

answer is A.

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Detailed Solution

Solution Explanation

  1. Structure of Benzene:

    Benzene has a hexagonal ring with six carbon atoms. Each carbon atom forms:

    • A sigma bond with one hydrogen atom.
    • Two sigma bonds with adjacent carbon atoms in the ring.
  2. Types of Bonds in Benzene:
    • Sigma Bonds (σ):
      • C-C Sigma Bonds: Each carbon is connected to two adjacent carbons via single covalent bonds. This makes 6 sigma bonds.
      • C-H Sigma Bonds: Each carbon is bonded to one hydrogen atom. This adds 6 more sigma bonds.
      • Total Sigma Bonds:6 + 6 = 12.
    • Pi Bonds (π):
      • Benzene has three alternating double bonds. Each double bond contains one π bond.
      • Total Pi Bonds:3.
  3. Calculating the Ratio:
    • Total π bonds = 3
    • Total σ bonds = 12
    • Ratio of π bonds to σ bonds = 3:12 = 1:4

Final Answer

The ratio of π bonds to σ bonds in benzene is 1:4.

This means that for every π bond in benzene, there are four σ bonds, reflecting the structure and bonding arrangement of the molecule.

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