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Q.

The ratio of spin-only magnetic moment value μeff[Cr(CN)6]3/μeff[Cr(H2O)6]3+ is __________.

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answer is 1.

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Detailed Solution

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In both [Cr(CN)6]3&[Cr(H2O)6]3+complex ions the central metal atom chromium is in +3 oxidation state, and has valence configuration 3d34s0.
Under both strong and weak field cases the configuration of Cr+3 is t2g3eg0 with three unpaired electrons (n = 3).
Spin only magnetic moment μs=n(n+2)=3(3+2)=15B.M
The ratio is 1 : 1
 

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