Q.

The ratio Cp,m/CV,m for linear triatomic molecules including vibration contribution is given by

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a

1.667

b

1.286

c

1.154

d

1.167

answer is C.

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Detailed Solution

The ratio Cp,m/CV,m for linear triatomic molecules including vibration contribution is given by 1.154.

For a triatomic molecule 

CV,m=32R+R+4R=132R; Cp,m=132R+R=152R

Hence, Cp,m/CV,m=15/13=1.154

Hence, the option C is correct.

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The ratio Cp,m/CV,m for linear triatomic molecules including vibration contribution is given by