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Q.

The reaction 2  O33  O2  Proceeds through the mechanism as below  
O3O2+O    (fast)O3+O2O2  (slow)
The rate law is given as

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a

r=k[o3]2  

b

r=k[o3]2[o2]

c

r=k[o3]2[o2]1

d

r=k[o3]  [o2]

answer is A.

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Detailed Solution

K=[O2][O]O3[O]=K[O3][O2]Rate=K[O3][O]Rate=K1[O3][O3][O2]=K[O3]2  [O2]1

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