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Q.

The reaction A2 + B22AB follows the mechanism
A2k1k1A+A(fast)
 A+B2k2 AB+B(slow) A+BAB(fast)

The overall order of the reaction is:

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a

1.5

b

3

c

2.5

d

2

answer is A.

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Detailed Solution

 rate =k2[A]B2(1)k1k1=[A]2A2[A]=k1k1A2

Substituting in (1) ; we get

 Rate =k2k1k1A212B2 order =32=1.5

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