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Q.

The reaction between X and Y is first order with respect to X and zero order with respect to Y

Experiment         [X]mol  L1       [Y]mol  L1      Initial  ratemol  L1min1

            I.                                 0.1                   0.1                  2×103

            II.                                 L                      0.2                     4×103

            III.                                0.4                  0.4                    M×103

            IV.                                0.1                   0.2                    2×103

            Examine the data of table and calculate ratio of numerical values of M and L. (Nearest Integer)

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answer is 40.

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Detailed Solution

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r=k[x][y]0=k[x]

Using I and II

Rate IVRate III=k[L]1k[0.1]1=4×1032×103=(L0.1)=L=0.2

Using III and IV

M×1032×103=k[0.4]k[0.1]M=8

ML=80.2=40

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