Q.

The reaction conditions leading to the best yield of  C2H5Cl are

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a

C2H6 (excess) +Cl2 uvlight 

b

C2H6+Cl2 dark  room temperature 

c

C2H6+Cl2 uv light 

d

C2H6+Cl2 (excess) 

answer is A.

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Detailed Solution

When chlorinating an alkane, the likelihood of mono-chlorination is higher if an excess of the alkane is treated with Cl2(g) in the presence of light or heat.

C2H6 (excess) +Cl2 UV-light CH3CH2Cl+HCl

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