Q.

The reaction of cyanamide, NH2CN(s) with oxygen was run in a bomb calorimeter and ΔU at 300 K was found to be 743 kJ mol1. The value of ΔH at 300 K for the combustion reaction.

NH2CN(s)+32O2(g)N2(g)+CO2(g)+H2O(l)

would be

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a

740.5 kJ mol1

b

744.25 kJ mol1

c

743 kJ mol1

d

741.75 kJ mol1

answer is A.

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Detailed Solution

ΔH=ΔU+ΔvgRT =743kJmol1+128.314×103kJK1mol1(300K) =741.75kJmol1

Thus the option A is correct.

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