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Q.

The reaction of hydrogen and iodine monochloride is given as :                                     H2(g) + 2ICl(g) 2HCl(g) + I2(g)  The reaction is of first order with respect to H2(g) and ICl(g). Following mechanisms were proposed.

Mechanism A :

H2(g) + 2ICl(g) 2HCl(g) + I2(g)

Mechanism B :

H2(g) + ICl(g) HI(g); slow

HI(g) + ICl(g) HCl(g) + I2(g): fast

Which of the above mechanism(s) can be consistent with the given information about the

reaction? 

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a

A and B both 

b

Neither A and B

c

A only

d

B only 

answer is D.

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Detailed Solution

As the slowest step is the rate determining step thus the mechanism B will be more

consistent with the given information also because it involve one molecule of H2and one

molecule of ICl it can expressed as r = k [H2][ICl]

which shows that the reaction is first order w.r.t. both H2 & ICl.

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