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Q.

The reaction of SOCl2 on alkanols to form alkyl chlorides gives good yields because

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a

Alcohol and SOCl2 are soluble in water

b

The reaction does not occur via intermediate formation of an alkyl chlorosulphite

c

The other products of the reaction are gaseous and escape out

d

Alkyl chlorides are immiscible with SOCl2

answer is B.

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Detailed Solution

ROH+SOCl2RCl(l)+HCl(g)+SO2(g)
The gaseous byproducts escape out on its own continuously driving the reaction in forward direction.

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