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Q.

The reaction that does NOT take place in a blast furnace between 900K to 1500 K temperature tange during extraction of iron is :

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a

CaO+SiO2CaSiO3

b

Fe2O3+CO2FeO+CO2

c

FeO+COFe+CO2

d

C+CO22CO

answer is B.

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Detailed Solution

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Fe2O3+CO2FeO+CO2 will occur at a temperature 500 - 800 K.
This reaction occurs at 500-1200k
3FeO3(s)+CO(g)2FeO4(s)+CO2(g)FeO4(s)+CO(g)3FeO(g)+CO2(g)
(1) This reaction occurs at 1200 K
CaCO3CaO+CO2
CaO+SiO2CaSiO3 (gangue)         (Slag)
(3) This reaction occurs at 500-800 K 
At higher temperature, some soot is formed by disproportionation of CO, which also reduces FeO to Fe
2CO(g)CO2(g)+C(s)FeO(s)+CFe(s)+CO(g)
(4) This reaction at 1800 K
CO2(g)+C(s)2CO(g) (endothermic)

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