Q.

The reaction that occurs in a 'breathlyser', a device used to determine the alcohol level in a person's blood stream, is :

2K2Cr2O7+8H2SO4+3C2H5OH 2Cr2SO43+2K2SO4+3CH3COOH+11H2O

If the rate of disappearance of ethanol is 6.9 gm/min, then the rate of appearance of chromium(III) sulphate is 

: (Cr= 52)

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a

88.2gm/min

b

39.2gm/min

c

4.6 gm/min

d

10.35gm/min

answer is C.

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Detailed Solution

Here,

dC2N5OHdt=6.9gm/min=6.946mole/min13dC2H5OH4dt=12dC25O43dt

Now, in C2SO43,

2×52+3(32+64) =392

Thus,

0.1×392=39.2gm/min

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