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Q.

The reaction which occur in the Galvanic cell is 
MnO4+8H++5Fe2+Mn2++5Fe3++4H2OEMnO4,Mn2+,H+Pt=1.51V and EFe3+,Fe2+Pt=0.77V
(Q) Calculate the standard emf of cell.

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a

0.74 V

b

-0.74 V

c

2.28

d

-2.28

answer is A.

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Detailed Solution

Ecell =EH+,Mn2+,MnO4PtEFe3+,Fe2+Pt=1.51(0.77)=+0.74V

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