Q.

The reaction AB follows first order kinetics. The time taken for 0.8 mole of A to produce 0.6 moles of B in 1 hour. What is the time taken for conversion of 0.9 mole of A to produces 0.675 moles of B?

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a

2 hours

b

0.5 hour

c

1 hour

d

0.25 hours

answer is A.

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Detailed Solution

A B                         A B

t=0    0.8        0       t=0    0.9          0 

t=t      0.2       0.6   t=t    0.225      0.675

K1=K2

2.3031log0.80.2=2.303xlog0.90.225

x=1 hr

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The reaction A→B follows first order kinetics. The time taken for 0.8 mole of A to produce 0.6 moles of B in 1 hour. What is the time taken for conversion of 0.9 mole of A to produces 0.675 moles of B?